Hydrochemistry of the meltwater streams on Fildes Peninsula, King George Island, Antarctica -- Journal of Oceanology and Limnology,2018,36(6):2181-2193

	Cite this paper:
	YE Liping, ZHANG Ruifeng, SUN Qizhen, JIN Jie, ZHANG Jing. Hydrochemistry of the meltwater streams on Fildes Peninsula, King George Island, Antarctica[J]. Journal of Oceanology and Limnology, 2018, 36(6): 2181-2193

Hydrochemistry of the meltwater streams on Fildes Peninsula, King George Island, Antarctica

YE Liping¹, ZHANG Ruifeng^1,2, SUN Qizhen³, JIN Jie¹, ZHANG Jing¹

1 State Key Laboratory of Estuarine and Coastal Research, East China Normal University, Shanghai 200062, China;
2 Institute of Oceanography, Shanghai Jiao Tong University, Shanghai 200030, China;
3 Department of Polar Research and Forecast, National Marine Environmental Forecasting Center, Beijing 100081, China

Abstract:

King George Island, situated in the South Shetland Islands archipelago, is one of the most visited sites in Antarctica. Antarctica attracts much attention because it is one of the most sensitive areas under the influence of global warming. To understand its hydrochemistry characteristics, we collected various types of water samples, including samples from streams, meltwaters, ground waters, snow and ice from around the Great Wall Station, Fildes Peninsula, King George Island, from January to February, 2015. Major ions, alkalinities, silicate, pH, dissolved oxygen, temperature, and electric conductivities were measured. Several approaches were applied to identify processes that affect the hydrochemistry on Fildes Peninsula, including ternary diagrams, principal components analysis and cluster analysis. Our data suggest that atmospheric seasalt deposition is the main factor controlling the hydrochemistry on Fildes Peninsula. After atmospheric influences were corrected for seasalt, we defined the weathering of local rocks to be another important factor on the Peninsula's hydrochemistry. Processes such as Ca dissolution from the Ca-bearing basalt, Si loss through secondary mineralization and biological uptake influence the chemical composition of runoffs on the peninsula. Cluster analysis identified 4 groups of streams based on their hydrochemical features, which reflect their original weathering characters under icecap and the combined effects with melt snow, biological activity and the anthropogenic input.

Received: 2017-07-03 Revised:

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References:
Alfonso J A, Vasquez Y, Hernandez A C, Mora A, Handt H, Sira E. 2015. Geochemistry of recent lacustrine sediments from Fildes Peninsula, King George Island, maritime Antarctica. Antarctic Science, 27(5):462-471.
Bhatia M P, Kujawinski E B, Das S B, Breier C F, Henderson P B, Charette M A. 2013. Greenland meltwater as a significant and potentially bioavailable source of iron to the ocean. Nature Geoscience, 6(4):274-278.
Borghini F, Bargagli R. 2004. Changes of major ion concentrations in melting snow and terrestrial waters from northern Victoria Land, Antarctica. Antarctic Science, 16(2):107-115.
Brandini F P. 1993. Phytoplankton biomass in an Antarctic coastal environment during stable water conditionsimplications for the iron limitation theory. Marine Ecology Progress Series, 93:267-275.
Brown G H. 2002. Glacier meltwater hydrochemistry. Applied Geochemistry, 17(7):855-883.
Cook A J, Fox A J, Vaughan D G, Ferrigno J G. 2005. Retreating glacier fronts on the Antarctic Peninsula over the past half-century. Science, 308(5721):541-544.
Cornelis J T, Delvaux B, Georg R B, Lucas Y, Ranger J, Opfergelt S. 2011. Tracing the origin of dissolved silicon transferred from various soil-plant systems towards rivers:a review. Biogeosciences, 8(1):89-112.
Dee D P, Uppala S M, Simmons A J, Berrisford P, Poli P, Kobayashi S, Andrae U, Balmaseda M A, Balsamo G, Bauer P, Bechtold P, Beljaars A C M, van de Berg L, Bidlot J, Bormann N, Delsol C, Dragani R, Fuentes M, Geer A J, Haimberger L, Healy S B, Hersbach H, Hólm E V, Isaksen L, Kållberg P, Köhler M, Matricardi M, McNally A P, Monge-Sanz B M, Morcrette J J, Park B K, Peubey C, de Rosnay P, Tavolato C, Thépaut J N, Vitart F. 2011. The ERA-Interim reanalysis:configuration and performance of the data assimilation system. Quarterly Journal of the Royal Meteorological Society, 137(656):553-597.
Dong Z W, Qin D H, Kang S C, Liu Y J, Li Y, Huang J, Qin X. 2016. Individual particles of cryoconite deposited on the mountain glaciers of the Tibetan Plateau:insights into chemical composition and sources. Atmospheric Environment, 138:114-124.
Dong Z W, Qin D H, Qin X, Cui J Y, Kang S C. 2017. Changes in precipitating snow chemistry with seasonality in the remote Laohugou glacier basin, western Qilian Mountains.Environmental Science and Pollution Research, 24(12):11 404-11 414.
Einarsson M Á. 1984. Climate of Iceland. In:van Loon H ed.World Survey of Climatology, Vol 15:Climates of the Oceans. Elsevier, Amsterdam. p.673-697.
European Centre for Medium-Range Weather Forecasts. 2009.Updated monthly. ERA-Interim project. Research data archive at the national center for atmospheric research, computational and information systems laboratory.https://doi.org/10.5065/D6CR5RD9. Accessed on 2016-11-25.
Fegel T S, Baron J S, Fountain A G, Johnson G F, Hall E K. 2016. The differing biogeochemical and microbial signatures of glaciers and rock glaciers. Journal of Geophysical Research:Biogeosciences, 121(3):919-932.
Gaillardet J, Dupré B, Louvat P, Allègrea C J. 1999. Global silicate weathering and CO₂ consumption rates deduced from the chemistry of large rivers. Chemical Geology, 159(1-4):3-30.
Georg R B, Reynolds B C, West A J, Burton K W, Halliday A N. 2007. Silicon isotope variations accompanying basalt weathering in Iceland. Earth and Planetary Science Letters, 261(3-4):476-490.
Gerringa L J A, Alderkamp A C, Laan P, Thuróczy C E, De Baar H J W, Mills M M, van Dijken G L, van Haren H, Arrigo K R. 2012. Iron from melting glaciers fuels the phytoplankton blooms in Amundsen Sea (Southern Ocean):iron biogeochemistry. Deep Sea Research Part Ⅱ:Topical Studies in Oceanography, 71-76:16-31.
Gislason S R, Arnorsson S, Armannsson H. 1996. Chemical weathering of basalt in southwest iceland:effects of runoff, age of rocks and vegetative glacial cover. American Journal of Science, 296(8):837-907.
Goyet C, Poisson A. 1989. New determination of carbonic acid dissociation constants in seawater as a function of temperature and salinity. Deep Sea Research Part A.Oceanographic Research Papers, 36(11):1 635-1 654.
Graly J A, Drever J I, Humphrey N F. 2017. Calculating the balance between atmospheric CO₂ drawdown and organic carbon oxidation in subglacial hydrochemical systems.Global Biogeochemical Cycles, 31(4):709-727.
Graly J A, Humphrey N F, Landowski C M, Harper J T. 2014.Chemical weathering under the Greenland ice sheet.Geology, 42(6):551-554.
Green W J, Stage B R, Preston A, Wagers S, Shacat J, Newell S. 2005. Geochemical processes in the Onyx River, Wright Valley, Antarctica:Major ions, nutrients, trace metals. Geochimica et Cosmochimica Acta, 69(4):839-850.
Grosbois C, Négrel P, Fouillac C, Grimaud D. 2000. Dissolved load of the Loire River:chemical and isotopic characterization. Chemical Geology, 170(1-4):179-201.
Hawkings J R, Wadham J L, Benning L G, Hendry K R, Tranter M, Tedstone A, Nienow P, Raiswell R. 2017. Ice sheets as a missing source of silica to the polar oceans. Nature Communications, 8:14 198.
Hodson A, Tranter M, Gurnell A, Clark M, Hagen J O. 2002.The hydrochemistry of Bayelva, a high Arctic proglacial stream in Svalbard. Journal of Hydrology, 257(1-4):91-114.
Hodson A, Tranter M, Vatne G. 2000. Contemporary rates of chemical denudation and atmospheric CO₂ sequestration in glacier basins:an Arctic perspective. Earth Surface Processes and Landforms, 25(13):1 447-1 471.
Hu M H, Stallard R F, Edmond J. 1982. Major ion chemistry of some large Chinese rivers. Nature, 298(5874):550-553.
Ingri J, Widerlund A, Land M. 2005. Geochemistry of major elements in a pristine boreal river system; hydrological compartments and flow paths. Aquatic Geochemistry, 11(1):57-88.
Jacobson A D, Grace Andrews M, Lehn G O, Holmden C. 2015. Silicate versus carbonate weathering in Iceland:new insights from Ca isotopes. Earth and Planetary Science Letters, 416:132-142.
Kejna M, Araźny A, Sobota I. 2013. Climatic change on King George Island in the years 1948-2011. Polish Polar Research, 34(2):213-235.
Keys J R, Williams K. 1981. Origin of crystalline, cold desert salts in the McMurdo region, Antarctica. Geochimica et Cosmochimica Acta, 45(12):2 299-2 309.
Leal M A, Joppert M, Licínio M V, Evangelista H, Maldonado J, Dalia K C, Lima C, Barros Leite C V, Correa S M, Medeiros G, da Cunha K D. 2008. Atmospheric impacts due to anthropogenic activities in remote areas:the case study of Admiralty Bay/King George Island/Antarctic Peninsula. Water, Air, and Soil Pollution, 188(1-4):67-80.
Li T T, Ji H B, Jiang Y B, Wang L X. 2007. Hydro-geochemistry and the sources of DIC in the upriver tributaries of the Ganjiang River. Acta Geographica Sinica, 62(7):764-775.
Li T, Lu Y H, Li Y L, Zhu M X, Yang G M. 2013. Progress in studies of the apparent dissociation equilibrium constants of carbonate system of seawater. Transactions of Oceanology and Limnology, (3):115-122. (in Chinese with English abstract)
Lim H S, Park Y, Lee J Y, Yoon H I. 2014. Geochemical characteristics of meltwater and pondwater on Barton and Weaver Peninsulas of King George Island, West Antarctica. Geochemical Journal, 48(4):409-422.
Liu X H, Zheng X S. 1988. Geology of volcanic rocks on Fildes Peninsula, King George Island, West Antarctica.Antarctic Research, 1(1):25-35. (in Chinese with English abstract)
Marshall W L, Franck E U. 1981. Ion product of water substance, 0-1000℃, 1-10,000 bars new international formulation and its background. Journal of Physical and Chemical Reference Data, 10(2):295-304.
Mebeck M. 1987. Global chemical weathering of surficial rocks estimated from river dissolved loads. American Journal of Science, 287(5):401-428.
Meybeck M. 1983. Atmospheric inputs and river transport of dissolved substances. IAHS Publ., 141:173-192.
Millero F J, Feistel R, Wright D G, McDougall T J. 2008. The composition of Standard Seawater and the definition of the reference-composition salinity scale. Deep Sea Research Part I:Oceanographic Research Papers, 55(1):50-72.
Millero F J, Graham T B, Huang F, Bustos-Serrano H, Pierrot D. 2006. Dissociation constants of carbonic acid in seawater as a function of salinity and temperature. Marine Chemistry, 100(1-2):80-94.
Navarre-Sitchler A, Brantley S. 2007. Basalt weathering across scales. Earth and Planetary Science Letters, 261(1-2):321-334.
Nędzarek A, Pociecha A. 2010. Limnological characterization of freshwater systems of the Thomas Point Oasis(Admiralty Bay, King George Island, West Antarctica).Polar Science, 4(3):457-467.
Nowak A, Hodson A. 2014. Changes in meltwater chemistry over a 20-year period following a thermal regime switch from polythermal to cold-based glaciation at Austre Brøggerbreen, Svalbard. Polar Research, 33(1):22 779.
Ólafsson H, Furger M, Brümmer B. 2007. The weather and climate of Iceland. Meteorologische Zeitschrift, 16(1):5-8.
Pokrovsky O S, Schott J, Kudryavtzev D I, Dupré B. 2005.Basalt weathering in Central Siberia under permafrost conditions. Geochimica et Cosmochimica Acta, 69(24):5 659-5 680.
Quayle W C, Peck L S, Peat H, Ellis-Evans J C, Harrigan P R. 2002. Extreme responses to climate change in Antarctic lakes. Science, 295(5555):645.
Raiswell R, Benning L G, Tranter M, Tulaczyk S. 2008.Bioavailable iron in the Southern Ocean:the significance of the iceberg conveyor belt. Geochemical Transactions, 9(1):7.
Raiswell R, Thomas A G. 1984. Solute acquisition in glacial melt waters. I. Fjallsjökull (South-East Iceland):bulk melt waters with closed-system characteristics. Journal of Glaciology, 30(104):35-43.
Rückamp M, Blindow N, Suckro S, Braun M, Humbert A. 2010. Dynamics of the ice cap on King George Island, Antarctica:field measurements and numerical simulations.Annals of Glaciology, 51(55):80-90.
Rückamp M, Braun M, Suckro S, Blindow N. 2011. Observed glacial changes on the King George Island ice cap, Antarctica, in the last decade. Global and Planetary Change, 79(1-2):99-109.
Schmid T, López-Martínez J, Guillaso S, Serrano E, D'Hondt O, Koch M, Nieto A, O'Neill T, Mink S, Durán J J, Maestro A. 2017. Geomorphological mapping of ice-free areas using polarimetric RADARSAT-2 data on Fildes Peninsula and Ardley Island, Antarctica. Geomorphology, 293:448-459.
Sharp M, Tranter M, Brown G H, Skidmore M. 1995. Rates of chemical denudation and CO₂ drawdown in a glaciercovered alpine catchment. Geology, 23(1):61-64.
Shi T T. 2012. The carbon sequestration effect of water cycle in a karst basin:a case study of Xiangxi River Basin, Hubei.Doctoral dissertation, China University of Geosciences(Wuhan), Wuhan, China. (in Chinese with English abstract)
Shin D, Lee J I, Hwang J, Hur S D. 2009. Hydrothermal alteration and isotopic variations of igneous rocks in Barton Peninsula, King George Island, Antarctica.Geosciences Journal, 13(1):103-112.
Stumpf A R, Elwood Madden M E, Soreghan G S, Hall B L, Keiser L J, Marra K R. 2012. Glacier meltwater stream chemistry in Wright and Taylor Valleys, Antarctica:significant roles of drift, dust and biological processes in chemical weathering in a polar climate. Chemical Geology, 322-323:79-90.
Torres M A, Moosdorf N, Hartmann J, Adkins J F, West A J. 2017. Glacial weathering, sulfide oxidation, and global carbon cycle feedbacks. Proceedings of the National Academy of Sciences of the United States of America, 114(33):8 716-8 721.
Tranter M. 1996. Glacial runoff as a sink for atmospheric CO₂ during the last glacial-interglacial transition. In:Proceedings of the Fourth International Symposium on the Geochemistry of the Earth's Surface. International Symposium on the Geochemistry of the Earth's Surface, Ilkley. p.709-713.
Vaughan D G, Marshall G J, Connolley W M, Parkinson C, Mulvaney R, Hodgson D A, King J C, Pudsey C J, Turner J. 2003. Recent rapid regional climate warming on the Antarctic Peninsula. Climatic Change, 60(3):243-274.
Wadham J L, Tranter M, Skidmore M, Hodson A J, Priscu J, Lyons W B, Sharp M, Wynn P, Jackson M. 2010.Biogeochemical weathering under ice:size matters.Global Biogeochemical Cycles, 24(3):GB3025.
Wadham J, Hodson A, Tranter M, Dowdeswell J A. 1998. The hydrochemistry of meltwaters draining a polythermal-based, high Arctic glacier, south Svalbard:I. The ablation season. Hydrological Processes, 12(12):1 825-1 849.
Wen J H, Kang J C, Han J K, Xie Z C, Liu L B, Wang D L. 1998. Glaciological studies on the King George Island ice cap, South Shetland Islands, Antarctica. Annals of Glaciology, 27(1):105-109.
Wong G J, Hawley R L, Lutz E R, Osterberg E C. 2013. Traceelement and physical response to melt percolation in Summit (Greenland) snow. Annals of Glaciology, 54(63):52-62.
Wu W H, Zheng H B, Yang J D, Luo C. 2012. Review and advancements of studies on silicate weathering and the global carbon cycle. Geological Journal of China Universities, 18(2):215-224. (in Chinese with English abstract)
Xu G J, Chen L Q, Zhang Y H, Wang J J, Li W, Lin Q. 2011.Chemical composition characteristics of marine aerosols collected on the route of the 26th Chinese national antarctic research expedition. Chinese Journal of Polar Research, 23(2):98-107. (in Chinese with English abstract)
Yang S, Zhang W, Shen X. 1990. Ground temperature and rock thermophysical properties in Fildes Peninsula. Antarctic Research, 1(1):58-66.
Yde J C, Knudsen N T, Nielsen O B. 2005. Glacier hydrochemistry, solute provenance, and chemical denudation at a surge-type glacier in Kuannersuit Kuussuat, Disko Island, West Greenland. Journal of Hydrology, 300(1-4):172-187.
Zhang R F, John S G, Zhang J, Ren J L, Wu Y, Zhu Z Y, Liu S M, Zhu X C, Marsay C M, Wenger F. 2015. Transport and reaction of iron and iron stable isotopes in glacial meltwaters on Svalbard near Kongsfjorden:from rivers to estuary to ocean. Earth and Planetary Science Letters, 424:201-211.
Zhou M, Zhu Y, Measures C I, Hatta M, Charette M A, Gille S T, Frants M, Jiang M S, Greg Mitchell B. 2013. Winter mesoscale circulation on the shelf slope region of the southern Drake Passage. Deep Sea Research Part Ⅱ:Topical Studies in Oceanography, 90:4-14.
Zhu C, Han X, Tan L. 2006. Experiment of Seawater Analytical Chemistry. China Ocean University Press, Qingdao, China. (in Chinese)